You can introduce solids any time between 4 months to 6 months if your baby is ready.
Cues to look for if your baby is ready for solids:
*Head control. Your baby needs to be able to keep his head in a steady upright position.
*To keep solid food in his mouth and then swallow it.
*Sitting well whe supported.
*Your baby's mouth and tongue develop in sync with his digestive system.
You can read more about starting solids from:
http://www.babycenter.com/0_introducing-solids_113.bc
You can consider buying the bumbo chair to help your baby sit up right.